Overall Score3.5
- Generality
- Reagent Availability
- Experimental User Friendliness
- Criteria #4
- Criteria #5
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General Characteristics
The hydroxyl radical generated from H2O2 in the presence of iron(II) is used to promote various decomposition reactions. Copper(I) is known to have a similar property as well.
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General References
- Fenton, H. J. H. Proc. Chem. Soc. 1893, 9, 113.
- Jenner, E. L. Org. Synth. Coll. Vol. 5, 1026 (1973). [website]
- Walling, C. Acc. Chem. Res. 1975, 8, 125. DOI: 10.1021/ar50088a003
- Tezuka, T.; Narita, N.; Ando, W.; Oae, S. J. Am. Chem. Soc. 1981, 103, 3045. DOI:10.1021/ja00401a023
- Walling, C.; Amarnath, K. J. Am. Chem. Soc. 1982, 104, 1185. DOI: 10.1021/ja00369a005
- Oturan, M. A. et al. New J. Chem. 1999, 23, 793. DOI: 10.1039/A903791H
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Reaction Mechanism
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Examples
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Experimental Procedure
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Experimental Tips
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References
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Related Reactions
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Related Books
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External Links