General Characteristics Grignard reagents are the most popular among organometallic reagents. Alkyl groups can be introduced into carbonyl compounds to give the corresponding alcohols. The ...
Tag Archives: organometallic
Complex Acid Chlorides from Unsaturated Hydrocarbons
Morandi at Max-Planck-Institut für Kohlenforschung developed an exchange reaction for producing functionalized acid chlorides． “CO- and HCl-free synthesis of acid chlorides from unsaturated ...
Manuel Alcarazo
Manuel Alcarazo (born in 1978, Spain) is a Professor at the University of Göttingen. (The photo is quoted from the laboratory HP) Education and Experiences 2005 PhD, the Instituto de Investigaciones ...
Spiroketal-Based Diphosphine Ligands in Pd-Catalyzed Asymmetric Allylic Amination of Morita−Baylis−Hillman Adducts: Exceptionally High Efficiency and New Mechanism
Wang, X.; Guo, P.; Han, Z.; Wang, X.; Wang, Z.; Ding, K. J. Am. Chem. Soc. 2014, 136, 405–411. DOI: 10.1021/ja410707q Exceptionally high activity (with a TON up to 4750) of the palladium complexes of ...
Rhodium-Catalyzed Three-Component Cross-Addition of Silylacetylenes, Alkynyl Esters, and Electron-Deficient Alkenes or Isocyanates
Hoshino, Y.; Shibata, Yu.; Tanaka, K.; Angew. Chem. Int. Ed. 2012, Early View. DOI: 10.1002/anie.201204646 ’Rh’oad crossing: A cationic RhI/(cod)2 complex catalyzes the chemo-, regio-, and ...
Decarbonylative C–H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A
Amaike, K.; Muto, K.; Yamaguchi, J.; Itami, K. J. Am. Chem. Soc., 2012, 134 , 13573–13576. DOI: 10.1021/ja306062c A nickel-catalyzed decarbonylative C–H biaryl coupling of azoles and aryl ...