Abstract The reactivity of organometallic reagents is roughly determined by the degree of polarization of carbon-metal bonds, with carbon-lithium bonds exhibiting the greatest polarization (ionic ...
Tag Archives: organometallic
Grignard Reaction
General Characteristics Grignard reagents are the most popular among organometallic reagents. Alkyl groups can be introduced into carbonyl compounds to give the corresponding alcohols. The ...
Complex Acid Chlorides from Unsaturated Hydrocarbons
Morandi at Max-Planck-Institut für Kohlenforschung developed an exchange reaction for producing functionalized acid chlorides． “CO- and HCl-free synthesis of acid chlorides from unsaturated ...
Manuel Alcarazo
Manuel Alcarazo (born in 1978, Spain) is a Professor at the University of Göttingen. (The photo is quoted from the laboratory HP) Education and Experiences 2005 PhD, the Instituto de Investigaciones ...
Spiroketal-Based Diphosphine Ligands in Pd-Catalyzed Asymmetric Allylic Amination of Morita−Baylis−Hillman Adducts: Exceptionally High Efficiency and New Mechanism
Wang, X.; Guo, P.; Han, Z.; Wang, X.; Wang, Z.; Ding, K. J. Am. Chem. Soc. 2014, 136, 405–411. DOI: 10.1021/ja410707q Exceptionally high activity (with a TON up to 4750) of the palladium complexes of ...
Rhodium-Catalyzed Three-Component Cross-Addition of Silylacetylenes, Alkynyl Esters, and Electron-Deficient Alkenes or Isocyanates
Hoshino, Y.; Shibata, Yu.; Tanaka, K.; Angew. Chem. Int. Ed. 2012, Early View. DOI: 10.1002/anie.201204646 ’Rh’oad crossing: A cationic RhI/(cod)2 complex catalyzes the chemo-, regio-, and ...
Decarbonylative C–H Coupling of Azoles and Aryl Esters: Unprecedented Nickel Catalysis and Application to the Synthesis of Muscoride A
Amaike, K.; Muto, K.; Yamaguchi, J.; Itami, K. J. Am. Chem. Soc., 2012, 134 , 13573–13576. DOI: 10.1021/ja306062c A nickel-catalyzed decarbonylative C–H biaryl coupling of azoles and aryl ...