Tag Archives: free radical

Minisci Reaction

Minisci Reaction

General Characteristics The Minisci reaction allows for the direct functionalization of electron deficient hetero aromatic rings with carbon radicals. The radical precursor is most commonly the ...

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Barton-McCombie Deoxygenation

Barton-McCombie Deoxygenation

General Characteristics The free radical-mediated deoxygenation of alcohol compounds after the formation of thiocarbonyl intermediates is known as the Barton-MacCombie deoxygenation. This reaction is ...

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Fukuyama Indole Synthesis

Fukuyama Indole Synthesis

General Characteristics The Fukuyama indole synthesis is a powerful way to synthesize 3-substituted or 2,3-disubstituted indoles using a radical initiator and tributyltin hydride. The second ...

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Wohl-Ziegler Bromination

Wohl-Ziegler Bromination

General Characteristics -The Wohl-Ziegler reaction is the free radical-based bromination of allylic and benzylic positions using N-bromosuccinimide (NBS). The solvents stable under free radical ...

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