Tag Archives: C–H activation

Tungstate Photocatalyst

Tungstate Photocatalyst

General Characteristics Tetrakis(tetrabutylammonium) decatungstate (TBADT) is an organic solvent-soluble polyoxometalate compound that can act as a C-H abstraction catalyst under UV-activated ...

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Catellani Reaction

Catellani Reaction

General Characteristics The Catellani reaction is a type of three component reaction in which the Mizoroki-Heck reaction and ortho C-H alkylation with alkyl halide occur concomitantly in the presence ...

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Hartwig-Miyaura C-H Borylation

Hartwig-Miyaura C-H Borylation

General Characteristics Iridium catalysts coordinated with electron-donating bidentate ligands promote direct C-H borylation of non-halogenated aromatic rings. Organoboronate compounds are, of ...

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Kharasch-Sosnovsky Oxidation

Kharasch-Sosnovsky Oxidation

General Characteristics Allylic C-H oxidation can be effected using acylperoxide under copper-catalyzed conditions. The alkene starting materials are usually used in excess. The terminal olefins are ...

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Catalytic C-H Oxidation

Catalytic C-H Oxidation

General Characteristics Catalytic C-H oxidation is a type of C-H activation reactions by which one can oxygenate unreactive C-H bonds, which are present ubiquitously in organic compounds. The C-H ...

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Fujiwara-Moritani Reaction

Fujiwara-Moritani Reaction

General Characteristics The direct coupling between unsubstituted aromatic rings and olefins in the presence of palladium catalysts is called the Fujiwara-Moritani reaction. This reaction is one of ...

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Du Bois Amination

Du Bois Amination

General Characteristics The direct amination of unactivated C-H bonds utilizing metal nitrenoids, especially with Rh-catalysis, became a practical synthetic option in the early 2000’s. This reaction ...

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