General Characteristics The phosphoric acids containing an appropriately substituted BINOL backbone function as chiral Brønsted acid catalysts that can promote a wide range of stereoselective ...
Tag Archives: organocatalyst
C-H Oxidation with NHPI Catalyst
Characteristics N-hydroxyphthalimide (NHPI) and related compounds have been revealed to be efficient organocatalysts for free-radical processes and have found ample application in promoting the ...
Spiroketal-Based Diphosphine Ligands in Pd-Catalyzed Asymmetric Allylic Amination of Morita−Baylis−Hillman Adducts: Exceptionally High Efficiency and New Mechanism
Wang, X.; Guo, P.; Han, Z.; Wang, X.; Wang, Z.; Ding, K. J. Am. Chem. Soc. 2014, 136, 405–411. DOI: 10.1021/ja410707q Exceptionally high activity (with a TON up to 4750) of the palladium complexes of ...
A General Aminocatalytic Method for the Synthesis of Aldimines
Morales, S.; Guijarro, F. G.; García Ruano, J. L.; Cid, M. B. J. Am. Chem. Soc. 2014, ASAP. DOI: 10.1021/ja4111418 A general and efficient biomimetic method for the synthesis of aldimines from ...