General Characteristics The derivatization of fullerenes using azomethine ylides via 1,3-dipoloar cycloaddition was developed by Prato. This methodology is applicable to carbon nanotubes as well. ...
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Michael Addition
General Characteristics The Michael reaction originally meant the 1,4-addition (conjugate addition) of simple anionic carbons to the electron poor double bonds conjugated to carbonyl groups. Today’s ...
Luche Reduction
General Characteristics -While 1,4-reduction usually predominates in the reduction of α,β-unsaturated ketones with NaBH4 alone, selective 1,2-reduction is possible using CeCl3-7H2O as an additive. ...
1,3-Dipolar Cycloaddition of Nitrone
Characteristics The 1,3-dipolar cycloaddition of nitrones, a kind of 1,3-dipole to unsaturated (C–C double or triple bond) compounds is one of the useful synthetic method for preparing isoxazole, ...