Posts by Category: Reactions

Bingel Reaction

Bingel Reaction

 Characteristics The Bingel reaction in fullerene chemistry is a fullerene cyclopropanation reaction to a methanofullerene first discovered by C. Bingel in 1993[a] with the bromo derivative of ...

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Dyotropic rearrangement

Dyotropic rearrangement

 Characteristics In 1972, M. T. Reetz originally defined dyotropic (from the greek dyo , meaning two) rearrangements as a new class of pericyclic valence isomerizations in which two σ ...

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Cheletropic Reaction

Cheletropic Reaction

 Characteristics Cheletropic reactions are types of pericyclic reaction. A type of addition reaction in which a conjugated molecule forms two single bonds from terminal atoms of the conjugated system ...

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Corey-Gilman-Ganem Oxidation

Corey-Gilman-Ganem Oxidation

Characteristics The Corey-Gilman-Ganem oxidation transforms benzylic or α,β-unsaturated aldehydes into the corresponding methyl esters. The aldehydes can be selectively oxidized to esters in presence ...

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Barton-Kellogg Reaction

Barton-Kellogg Reaction

Characteristics The Barton-Kellogg reaction is a coupling reaction between a ketone and a thioketone through a diazo intermediate forming an alkene.  The McMurry Reaction is similar to the ...

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Suzuki-Miyaura Cross Coupling

Suzuki-Miyaura Cross Coupling

Characteristics  A cross-coupling reaction between organoboron and organoboron and organohalide compounds via palladium catalysis, which was discovered by Akira Suzuki and Norio Miyaura (Hokkaido ...

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