El-Hellanid, A.; Lavallo, V. Angew. Chem. Int. Ed. 53, 2014. 4489-4493. DOI: 10.1002/anie.201402445 Fusion of two families of unusual carbon-containing molecules that readily disregard the tendency ...
Daily Archives: May 12, 2014
Kumada-Tamao-Corriu Cross Coupling
General Characteristics The palladium- or nickel-catalyzed cross coupling between aryl halides/triflates and Grignard reagents is known as the Kumada-Tamao-Corriu reaction. The Kumada-Tamao-Corriu ...
Malaprade Glycol Oxidative Cleavage
General Characteristics Periodic acid or sodium periodate is used to oxidatively cleave 1,2-diols, producing a pair of aldehydes or ketones. Sodium periodate also works as the reoxidant of osmium ...