General Characteristics The allylation reactions using allylsilanes are known as the Hosomi-Sakurai allylation. Allylsilanes are less toxic than allylstannanes and more stable than allyl Grignard and ...
Daily Archives: May 8, 2014
Sandmeyer Reaction
General Characteristics The transformation of aromatic diazonium compounds is known as the Sandmeyer reaction. Diazonium compounds are readily prepared from precursors such as nitro and aniline ...
Fukuyama Indole Synthesis
General Characteristics The Fukuyama indole synthesis is a powerful way to synthesize 3-substituted or 2,3-disubstituted indoles using a radical initiator and tributyltin hydride. The second ...
Tamao-Fleming Oxidation
General Characteristics Organosilicon compounds containing hetero atom substituent(s) on the silicon atom are oxidized by hydrogen peroxide in the presence of a fluoride source and a weak base. The ...