Characteristics Typically, the 1,2-diol is treated with Bu2SnX, where X = O or (OMe), with removal (azeotropic or desiccant) of either H2O or MeOH to afford the requisite stannylidenes (“tin ...
Daily Archives: February 26, 2014
#6 Prof. Jun Terao: Synthesizing electronic circuits
The sixth interview of this series is with Professor Jun Terao from the Graduate School of Engineering at Kyoto University, as suggested by Professor Kenichiro Itami at our second Chem-Station ...
Ichikawa Allylcyanate Rearrangement
Characteristics Ichikawa Allylcyanate rearrangement is [3.3] sigmatropic rearrangement of allyl cyanates to isocyanate. The rearrangement begins with dehydration of allyl carbamate by Appel ...