General Characteristics The direct amination of unactivated C-H bonds utilizing metal nitrenoids, especially with Rh-catalysis, became a practical synthetic option in the early 2000’s. This reaction ...
Tag Archives: rhodium carbenoid
Cyclopropanation with Metal Carbenoids
General Characteristics In the presence of metal catalysts, diazo compounds decompose to generate metal carbenoid species, which react with olefins to give cyclopropanes. Metal carbenoids also react ...