Tang, C.; Jiao, N.; Angew. Chem. Int. Ed. 2014, Early view. DOI:10.1002/anie.201403528 A novel copper-catalyzed aerobic oxidative C(CO)-C(alkyl) bond cleavage reaction of aryl alkyl ketones for C-N ...
Monthly Archives: June 2014
Takai-Uchimoto Olefination
General Characteristics -The synthesis of alkenyl halides from aldehydes using the gem-dichromium reagent prepared from haloform (CHX3) and CrCl2 is known as the Takai-Uchimoto reaction. Mild ...
Sharpless Asymmetric Dihydroxylation (Sharpless AD)
General Characteristics -Sharpless developed chiral ligands ((DHQD)2PHAL or (DHQ)2PHAL) derived from cinchona alkaloids (quinidine, quinine) for the practical osmium tetroxide-catalyzed asymmetric ...