McCarthy, S. M.; Lin, Y.-C.;Devarajan, D.;Chang, J. W.;Yennawar, H. P; Rioux, R. M.;Ess, D. H.;Radosevich, A. T. J. Am. Chem. Soc. 136, 2014. 136, 4640−4650 DOI: 10.1021/ja412469e Ammonia, alkyl ...
Author Archive
Enhancing the Versatility and Functionality of Fast Photochromic Bridged Imidazole Dimers by Flipping Imidazole Rings
K. Shima, K. Mutoh, Y. Kobayashi, J. Abe, J. Am. Chem. Soc. 2014, 136, 3796–3799. DOI: 10.1021/ja501028v The widely tunable optical properties and the visible sensitivity have been required for fast ...
The Existence of Hexafluoroarsenic(V) Acid
Axhausen, J.; Lux, K.; Kornath, A.Angew. Chem. Int. Ed. 2014. 53, Early View. DOI:10.1002/anie.201308023 The homogeneous mixture of anhydrous hydrogen fluoride aHF and antimony pentafluoride AsF5 is ...
![Crystal Structures of the Carborane Dianions [1,4-(PhCB10H10C)2C6H4]2- and [1,4-(PhCB10H10C)2C6F4]2- and the Stabilizing Role of the para-Phenylene Unit on 2n+3 Skeletal Electron Clusters](https://assets.en.chem-station.com/uploads/2014/04/for-toc.gif)
Crystal Structures of the Carborane Dianions [1,4-(PhCB10H10C)2C6H4]2- and [1,4-(PhCB10H10C)2C6F4]2- and the Stabilizing Role of the para-Phenylene Unit on 2n+3 Skeletal Electron Clusters
Kahlert, J.; Stammler, H.-G.;Neumann, B.; Harder, R. A.; Weber, L.; Fox, M. A. Angew. Chem. Int. Ed. 53, 2014. Early View. DOI: 10.1002/anie201310718 While carboranes with 2n+2 and 2n+4 (n= number of ...
Four-Step Synthesis of the Antimalarial Cardamom Peroxide via an Oxygen Stitching Strategy
X. Hu, T. J. Maimone, J. Am. Chem. Soc. 2014, 136, 5287–5290. DOI:10.1021/ja502208z A four-step synthesis of the antimalarial terpene cardamom peroxide, a 1,2-dioxepane-containing natural product, is ...
Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis
DiRocco, D. A.; Dykstra, K.; Krska, S.; Vachal, P.; Conway, D. V.; Tudge, M. Angew. Chem. Int. Ed. 2014, Early View. DOI: 10.1002/anie.201402023 The direct C–H functionalization of heterocycles has ...
Samuel J. Danishefsky
Samuel J. Danishefsky (born 1936, Bayonne, NJ) is synthetic organic chemist who accomplished in natural products total synthesis and pioneer for chemical synthesis of carbohydrates for the ...
Aromatic Homologation by Non-Chelate-Assisted RhIII-Catalyzed C–H Functionalization of Arenes with Alkynes
Pham, M. V.; Cramer, N. Angew. Chem. Int. Ed. 2014. Early View. DOI: 10.1002/anie.201310723 Larger condensed arenes are of interest owing to their electro- and photochemical properties. An efficient ...