Hadlington, T. J.; Hermann, M.; Frenking, G.; Jones, C. J. Am. Chem. Soc. 136, 2014. 136, 3028. DOI: 10.1021/ja5006477 This study details the first use of well-defined low-valent p-block metal ...
Posts by Category: OrganicChem
Stable GaX2, InX2 and TlX2 radicals
Protchenko, A. V.; Dange, D.; Harmer, J. R.; Tang, C. Y.; Schwarz, A. D.; Kelly, M. J.; Phillips, N.; Tirfoin, R.; Birjkumar, K. H.; Jones, C.; Kaltsoyannis, N.; Mountford. P; Aldridge, S. Nat. ...
Isolation of Bridging and Terminal Coinage Metal−Nitrene Complexes
Dielmann, F.; Andrada, D. M.; Frenking, G.; Bertrand, G. J. Am. Chem. Soc., 2014. 136, 3800. DOI: 10.1021/ja5007355 Transition metal complexes featuring a metal−nitrogen multiple bond have been ...
Arsa-Diazonium Salts with an Arsenic–Nitrogen Triple Bond
Kuprat, M.; Schulz, A.; Villinger, A. Angew. Chem. Int. Ed. 52, 2013. 7126 – 7130. DOI: 10.1002/anie.201302725 Arsa-diazonium salts containing a cation with an arsenic–nitrogen triple bond ...
Coordination Complexes of Ph3Sb2+ and Ph3Bi2+: Beyond Pnictonium Cations
Robertson, A. P. M.; Burford, N.; McDonald, R.; Ferguson, M. J. Angew. Chem. Int. Ed. 53, 2014. Early View. DOI: 10.1002/anie.201310613 The syntheses of salts containing ligand-stabilized Ph3Sb2+ and ...
Direct Hydroboration of B=B Bonds: A Mild Strategy for the Proliferation of B=B Bonds
Braunschweig, H.; Dewhurst, R. D.; Hcrl, C.; Phukan, A. K.; Pinzner, F.; Ullrich, S. Angew. Chem. Int. Ed. 53, 2014. Early View. DOI: 10.1002/anie.201309325 Synthetic access to electron-precise boron ...
Inorganic-Base-Mediated Hydroamination of Alkenyl Oximes for the Synthesis of Cyclic Nitrones
Peng, X.; Tong, M. K. B.; Hirao,H.; Chiba, S. Angew. Chem. Int. Ed. 53, 2014. 1959. DOI: 10.1002/anie.201308617 A method based on hydroamination mediated by inorganic base was developed for the ...
Oxidant-Free Conversion of Cyclic Amines to Lactams and H2 Using Water As the Oxygen Atom Source
Khusnutdinova, J. R.; Ben-David, Y.; Milstein, D. J. Am. Chem. Soc. 136, 2014. 2998. DOI: 10.1021/ja500026m Direct conversion of cyclic amines to lactams utilizing water as the only reagent is ...
Controlling a Polymer Adhesive Using Light and a Molecular Switch
Asadirad, A. M.; Boutault, S.; Erno, Z.; Branda, N. R. J. Am. Chem. Soc. 2014. ASAP DOI: 10.1021/ja500496n A thermally remendable polymer was synthesized by the Diels–Alder reaction between ...
A Mild Ni/Cu-Catalyzed Silylation via C–O Cleavage
Zárate, C.; Martin, R. J. Am. Chem. Soc. 2014, ASAP. DOI: 10.1021/ja412107b A Ni/Cu-catalyzed silylation of unactivated C–O electrophiles derived from phenols or benzyl alcohols is described. This ...