Axhausen, J.; Lux, K.; Kornath, A.Angew. Chem. Int. Ed. 2014. 53, Early View. DOI:10.1002/anie.201308023 The homogeneous mixture of anhydrous hydrogen fluoride aHF and antimony pentafluoride AsF5 is ...
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![Crystal Structures of the Carborane Dianions [1,4-(PhCB10H10C)2C6H4]2- and [1,4-(PhCB10H10C)2C6F4]2- and the Stabilizing Role of the para-Phenylene Unit on 2n+3 Skeletal Electron Clusters](https://assets.en.chem-station.com/uploads/2014/04/for-toc.gif)
Crystal Structures of the Carborane Dianions [1,4-(PhCB10H10C)2C6H4]2- and [1,4-(PhCB10H10C)2C6F4]2- and the Stabilizing Role of the para-Phenylene Unit on 2n+3 Skeletal Electron Clusters
Kahlert, J.; Stammler, H.-G.;Neumann, B.; Harder, R. A.; Weber, L.; Fox, M. A. Angew. Chem. Int. Ed. 53, 2014. Early View. DOI: 10.1002/anie201310718 While carboranes with 2n+2 and 2n+4 (n= number of ...
Four-Step Synthesis of the Antimalarial Cardamom Peroxide via an Oxygen Stitching Strategy
X. Hu, T. J. Maimone, J. Am. Chem. Soc. 2014, 136, 5287–5290. DOI:10.1021/ja502208z A four-step synthesis of the antimalarial terpene cardamom peroxide, a 1,2-dioxepane-containing natural product, is ...
Late-Stage Functionalization of Biologically Active Heterocycles Through Photoredox Catalysis
DiRocco, D. A.; Dykstra, K.; Krska, S.; Vachal, P.; Conway, D. V.; Tudge, M. Angew. Chem. Int. Ed. 2014, Early View. DOI: 10.1002/anie.201402023 The direct C–H functionalization of heterocycles has ...
Aromatic Homologation by Non-Chelate-Assisted RhIII-Catalyzed C–H Functionalization of Arenes with Alkynes
Pham, M. V.; Cramer, N. Angew. Chem. Int. Ed. 2014. Early View. DOI: 10.1002/anie.201310723 Larger condensed arenes are of interest owing to their electro- and photochemical properties. An efficient ...
A Concerted Transfer Hydrogenolysis: 1,3,2-Diazaphospholene-Catalyzed Hydrogenation of N=N Bond with Ammonia–Borane
Chong, C.-C.; Hirao, H.; Kinjo, R. Angew. Chem. Int. Ed. 53, 2014. Early View DOI: 10.1002/anie.201400099 1,3,2-diazaphospholenes catalyze metal-free transfer hydrogenation of a NN double bond using ...
Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds
Hadlington, T. J.; Hermann, M.; Frenking, G.; Jones, C. J. Am. Chem. Soc. 136, 2014. 136, 3028. DOI: 10.1021/ja5006477 This study details the first use of well-defined low-valent p-block metal ...
Stable GaX2, InX2 and TlX2 radicals
Protchenko, A. V.; Dange, D.; Harmer, J. R.; Tang, C. Y.; Schwarz, A. D.; Kelly, M. J.; Phillips, N.; Tirfoin, R.; Birjkumar, K. H.; Jones, C.; Kaltsoyannis, N.; Mountford. P; Aldridge, S. Nat. ...
Dismutational and Global-Minimum Isomers of Heavier 1,4-Dimetallatetrasilabenzenes of Group 14
Jana, A.; Huch, V.; Repisky, M.; Berger, R. J. F.; Scheschkewitz, D. Angew. Chem. Int. Ed., 2014. Early View DOI: 10.1002/anie.201310475 Aromatic species with heavier Group 14 elements show ...
Isolation of Bridging and Terminal Coinage Metal−Nitrene Complexes
Dielmann, F.; Andrada, D. M.; Frenking, G.; Bertrand, G. J. Am. Chem. Soc., 2014. 136, 3800. DOI: 10.1021/ja5007355 Transition metal complexes featuring a metal−nitrogen multiple bond have been ...